Benzimidazolone pigments first appeared on the German market in 1964. The relative order in which the seventeen generic structures, still available as pigments from Clariant, were launched in Europe, is listed in Table 10.3. As mentioned above, there are numerous manufacturers of benzimidazolone pigments today.
Since the introduction of this pigment class, they have successfully competed in the replacement of heavy metal-containing inorganic pigments in paints and plastics, and now form a most important group of organic yellows, oranges and reds.
Table 10.4 provides an overview of known suppliers and the physical form in which the pigments are offered. The data are adopted from the Colour Index [1].
Table 10.4 Known pigment brands and manufacturers of benzimidazolone pigments (as of 1997) [1].
C. I. name/ Trademark
|
Manufacturer
|
Main applications
|
Physical
form
|
P. Y. 120
|
|
|
|
Novoperm Yellow H2G
|
Clariant Intern. Ltd., CH
|
paint
|
powder
|
PV Fast Yellow H2G 01
|
Clariant Intern. Ltd., CH
|
plastics
|
powder
|
P. Y. 151
|
|
|
|
DCC 7151 Benzimid — azolone Yellow
|
Dominion Colour Corp., Canada
|
paint, plastics, printing inks
|
powder
|
Foscolor Yellow 151
|
Foscolor Ltd., UK
|
printing inks
|
masterbatch
|
Highlite Yellow 1205
|
Engelhard Corp., USA
|
paint, plastics
|
powder
|
Hostaperm Yellow H4G
|
Clariant Intern. Ltd., CH
|
paint
|
powder
|
Kenalake Yellow 4GO
|
Hays Colours, UK
|
paint
|
powder
|
Pigment Yellow 151
|
Member(s) of Color Pigments Manufacturing Association, USA
|
paint, plastics, printing inks
|
powder
|
PV Fast Yellow H4G
|
Clariant Intern. Ltd., CH
|
plastics
|
powder
|
Symuler Fast Yellow 4GO
|
Dainippon Ink & Chemicals Inc., JP
|
paint, plastics, printing inks
|
powder
|
Symuler Fast Yellow 4GO-E
|
Dainippon Ink & Chemicals Inc., JP
|
plastics
|
powder
|
Symuler Fast Yellow 4GT
|
Dainippon Ink & Chemicals Inc., JP
|
printing inks
|
powder
|
P. Y. 154
|
|
|
|
Chromofine Yellow 2080
|
Dainichiseika Color & Chemicals, JP
|
paint
|
powder
|
Colanyl Yellow H3G 100
|
Clariant Intern. Ltd., CH
|
paint
|
liquid
dispersion
|
|
Table 10.4 Continued
C. I. name/ Trademark
|
Manufacturer
|
Main applications
|
Physical
form
|
Flexobrite Yellow L3GA
|
Yorkshire Chemicals plc., UK
|
paint
|
powder
|
Hostaperm Yellow H3G
|
Clariant Intern. Ltd., CH
|
paint
|
powder
|
Symuler Fast Yellow 4192
|
Dainippon Ink & Chemicals Inc., JP
|
paint, printing inks
|
powder
|
P. Y. 175
|
|
|
|
Hostaperm Yellow H6G
|
Clariant Intern. Ltd., CH
|
paint
|
powder
|
Pigment Yellow 175
|
Member(s) of Color Pigments Manufacturing Association, USA
|
printing inks
|
powder
|
P. Y. 180
|
|
|
|
Hostaprint Yellow HG 31
|
Clariant Intern. Ltd., CH
|
pastics (PVC films and mass coloration)
|
powder
|
Hostasin Yellow HG
|
Clariant Intern. Ltd., CH
|
plastics (rubber)
|
granule
|
Novoperm Yellow P-HG
|
Clariant Intern. Ltd., CH
|
printing inks (solvent based package inks)
|
powder
|
PV Fast Yellow HG
|
Clariant Intern. Ltd., CH
|
plastics
|
powder
|
Toner Yellow HG
|
Clariant Intern. Ltd., CH
|
color toners
|
powder
|
Yellow EMD-352
|
Sumika Color Co. Ltd., JP
|
plastics
|
powder
|
Yellow KG
|
Keystone Aniline Corp., USA
|
plastics, printing inks and other
|
powder
|
Yellow PEC-352
|
Sumika Color Co. Ltd., JP
|
plastics (polyolefins)
|
granule
|
P. Y. 181
|
|
|
|
PV Fast Yellow H3R
|
Clariant Intern. Ltd., CH
|
plastics
|
powder
|
Yellow K3R
|
Keystone Aniline Corp., USA
|
plastics
|
powder
|
P. Y. 194
|
|
|
|
Novoperm Yellow F2G
|
Clariant Intern. Ltd., CH
|
paint, printing inks
|
powder
|
PV Fast Yellow F2G
|
Clariant Intern. Ltd., CH
|
plastics
|
powder
|
|
Table 10.4 Continued
C. I. name/ Manufacturer Main applications Physical
Trademark form
P. O. 36
DCC 7036 Benzimid — azolone Orange
|
Dominion Colour Corp., Canada
|
paint, plastics, printing inks
|
powder
|
Kenalake Orange HP-RLOX
|
Hays Colours, UK
|
paint
|
powder
|
Lysopac Orange 3620C
|
Cappelle, NV, Belgium
|
paint
|
powder
|
Novoperm Orange HL
|
Clariant Intern. Ltd., CH
|
paint
|
powder
|
Novoperm Orange HL 70
|
Clariant Intern. Ltd., CH
|
paint
|
powder
|
Novoperm Orange HL70-NF
|
Clariant Intern. Ltd., CH
|
paint
|
powder
|
Pigment Orange 36
|
Member(s) of Color Pigments Manufacturing Association, USA
|
paint, plastics, printing inks
|
powder
|
Sudaperm Orange 2915
|
Sudarshan Chemicals Ind. Ltd, India
|
paint, plastics and other
|
powder
|
Sunfast Orange 36 (271-9036)
|
Sun Chemical Corp., USA
|
paint
|
powder
|
Symuler Fast Orange 4183H
|
Dainippon Ink & Chemicals Inc., JP
|
paint, printing inks
|
powder
|
Yorabrite Orange HL
|
Yorkshire Chemicals plc, UK
|
paint, plastics, printing inks and other
|
liquid
dispersion
|
P. O. 62
|
|
|
|
Kenalake Orange HP-3GO
|
Hays Colours, UK
|
paint, printing inks
|
powder
|
Novoperm Orange H5G 70
|
Clariant Intern. Ltd., CH
|
paint
|
powder
|
P. O. 64
|
|
|
|
Cromophtal Orange GL
|
Ciba Speciality Chemicals Inc., CH
|
printing inks
|
powder
|
Cromophtal Orange GP
|
Ciba Speciality Chemicals
|
plastics, printing inks
|
powder
|
Inc., CH
|
10 Benzimidazolone Pigments and Related Structures Table 10.4 Continued
C. I. name/ Trademark
|
Manufacturer
|
Main applications
|
Physical
form
|
Hornapol Orange PO — 536-T
|
Ciba Speciality Chemicals Inc., CH
|
plastics
|
masterbatch
|
Orange EMD-218
|
Sumika Color Co. Ltd, JP
|
plastics
|
powder
|
Orange GP
|
Keystone Aniline Corp., USA
|
plastics, printing inks
|
powder
|
Orange PEC-218
|
Sumika Color Co. Ltd, JP
|
plastics
|
granule
|
Pigment Orange 64 P. O. 72
|
Member(s) of Color Pigments Manufacturing Association, USA
|
plastics, printing inks
|
powder
|
PV Fast Yellow H4GL01
|
Clariant Intern. Ltd., CH
|
plastics
|
powder
|
P. R. 175
|
Novoperm Red HFT
|
Clariant Intern. Ltd., CH
|
paint
|
powder
|
PV Fast Red HFT
|
Clariant Intern. Ltd., CH
|
plastics
|
powder
|
P. R. 176
|
Aquanyl P Carmine HF3C 13-3166
|
Clariant Intern. Ltd., CH
|
paint
|
powder
|
Flexonyl Carmine HF3C-LA
|
Clariant Intern. Ltd., CH
|
decorative laminates, paper
|
liquid
dispersion
|
Graphtol CarmineHF3C
|
Clariant Intern. Ltd., CH
|
printing inks
|
powder
|
PV Carmine HF3C
|
Clariant Intern. Ltd., CH
|
plastics
|
powder
|
P. R. 185
|
Epsilon Red LB-1TO28
|
Sumika Color Co. Ltd, JP
|
rubber
|
masterbatch
|
Hostaprint Carmine HF4C31
|
Clariant Intern. Ltd., CH
|
plastics
|
powder
|
Microlith Red 4C-K
|
Ciba Speciality Chemicals Inc., CH
|
paint, printing inks
|
powder
|
Novoperm Carmine HF4C
|
Clariant Intern. Ltd., CH
|
printing inks
|
powder
|
Pigment Red 185
|
Member(s) ofColor Pigments Manufacturing Association, USA
|
paint, printing inks
|
powder
|
Table 10.4 Continued
C. I. name/
|
Manufacturer
|
Main applications
|
Physical
|
Trademark
|
|
|
form
|
Graphtol Carmine HF4C
|
Clariant Intern. Ltd., CH
|
plastics
|
powder
|
Simperm Red AHE
|
WS Simpson & Co., UK
|
printing inks and other
|
powder
|
P. R. 208
|
|
|
|
Hostaprint Red HF2B 31
|
Clariant Intern. Ltd., CH
|
plastics
|
powder
|
Hostasin Red HF2B
|
Clariant Intern. Ltd., CH
|
Plastics (rubber)
|
granule
|
Novoperm Red HF2B 01
|
Clariant Intern. Ltd., CH
|
printing inks
|
powder
|
Graphtol Red HF2B 01
|
Clariant Intern. Ltd., CH
|
plastics
|
powder
|
Renol Red HF2B-HW
|
Clariant Intern. Ltd., CH
|
solvent based wood stains, marker inks
|
powder
|
P. V. 32
|
|
|
|
Hostaprint Bordeaux HF3R 31
|
Clariant Intern. Ltd., CH
|
plastics
|
powder
|
Novofil Bordeaux BB
|
Clariant Intern. Ltd., CH
|
coloration of viscose
|
liquid
dispersion
|
Novoperm Bordeaux HF3R
|
Clariant Intern. Ltd., CH
|
printing inks
|
powder
|
Graphtol Bordeaux HF3R
|
Clariant Intern. Ltd., CH
|
plastics
|
powder
|
P. Br. 25
|
|
|
|
Hostaprint Brown HFR 31
|
Clariant Intern. Ltd., CH
|
plastics
|
powder
|
Microdis Brown PSR
|
Colorom SA, Romania
|
other
|
paste
|
Microdis Yellowish
|
Colorom SA, Romania
|
other
|
paste
|
Brown IGT
|
|
|
|
Novofil Brown HFR
|
Clariant Intern. Ltd., CH
|
coloration of viscose
|
liquid
dispersion
|
PV Fast Brown HFR 01
|
Clariant Intern. Ltd., CH
|
plastics
|
powder
|
Renol Brown HFR-HW
|
Clariant Intern. Ltd., CH
|
solvent based wood stains and marker inks
|
powder
|
|
10.7
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