Pigment Manufacturers, Economics

Benzimidazolone pigments first appeared on the German market in 1964. The relative order in which the seventeen generic structures, still available as pigments from Clariant, were launched in Europe, is listed in Table 10.3. As mentioned above, there are numerous manufacturers of benzimidazolone pigments today.

Since the introduction of this pigment class, they have successfully competed in the replacement of heavy metal-containing inorganic pigments in paints and plas­tics, and now form a most important group of organic yellows, oranges and reds.

Table 10.4 provides an overview of known suppliers and the physical form in which the pigments are offered. The data are adopted from the Colour Index [1].

Table 10.4 Known pigment brands and manufacturers of benzimidazolone pigments (as of 1997) [1].

C. I. name/ Trademark

Manufacturer

Main applications

Physical

form

P. Y. 120

Novoperm Yellow H2G

Clariant Intern. Ltd., CH

paint

powder

PV Fast Yellow H2G 01

Clariant Intern. Ltd., CH

plastics

powder

P. Y. 151

DCC 7151 Benzimid — azolone Yellow

Dominion Colour Corp., Canada

paint, plastics, printing inks

powder

Foscolor Yellow 151

Foscolor Ltd., UK

printing inks

masterbatch

Highlite Yellow 1205

Engelhard Corp., USA

paint, plastics

powder

Hostaperm Yellow H4G

Clariant Intern. Ltd., CH

paint

powder

Kenalake Yellow 4GO

Hays Colours, UK

paint

powder

Pigment Yellow 151

Member(s) of Color Pigments Manufacturing Association, USA

paint, plastics, printing inks

powder

PV Fast Yellow H4G

Clariant Intern. Ltd., CH

plastics

powder

Symuler Fast Yellow 4GO

Dainippon Ink & Chemicals Inc., JP

paint, plastics, printing inks

powder

Symuler Fast Yellow 4GO-E

Dainippon Ink & Chemicals Inc., JP

plastics

powder

Symuler Fast Yellow 4GT

Dainippon Ink & Chemicals Inc., JP

printing inks

powder

P. Y. 154

Chromofine Yellow 2080

Dainichiseika Color & Chemicals, JP

paint

powder

Colanyl Yellow H3G 100

Clariant Intern. Ltd., CH

paint

liquid

dispersion

Table 10.4 Continued

C. I. name/ Trademark

Manufacturer

Main applications

Physical

form

Flexobrite Yellow L3GA

Yorkshire Chemicals plc., UK

paint

powder

Hostaperm Yellow H3G

Clariant Intern. Ltd., CH

paint

powder

Symuler Fast Yellow 4192

Dainippon Ink & Chemicals Inc., JP

paint, printing inks

powder

P. Y. 175

Hostaperm Yellow H6G

Clariant Intern. Ltd., CH

paint

powder

Pigment Yellow 175

Member(s) of Color Pigments Manufacturing Association, USA

printing inks

powder

P. Y. 180

Hostaprint Yellow HG 31

Clariant Intern. Ltd., CH

pastics (PVC films and mass coloration)

powder

Hostasin Yellow HG

Clariant Intern. Ltd., CH

plastics (rubber)

granule

Novoperm Yellow P-HG

Clariant Intern. Ltd., CH

printing inks (solvent based package inks)

powder

PV Fast Yellow HG

Clariant Intern. Ltd., CH

plastics

powder

Toner Yellow HG

Clariant Intern. Ltd., CH

color toners

powder

Yellow EMD-352

Sumika Color Co. Ltd., JP

plastics

powder

Yellow KG

Keystone Aniline Corp., USA

plastics, printing inks and other

powder

Yellow PEC-352

Sumika Color Co. Ltd., JP

plastics (polyolefins)

granule

P. Y. 181

PV Fast Yellow H3R

Clariant Intern. Ltd., CH

plastics

powder

Yellow K3R

Keystone Aniline Corp., USA

plastics

powder

P. Y. 194

Novoperm Yellow F2G

Clariant Intern. Ltd., CH

paint, printing inks

powder

PV Fast Yellow F2G

Clariant Intern. Ltd., CH

plastics

powder

Table 10.4 Continued

C. I. name/ Manufacturer Main applications Physical

Trademark form

P. O. 36

DCC 7036 Benzimid — azolone Orange

Dominion Colour Corp., Canada

paint, plastics, printing inks

powder

Kenalake Orange HP-RLOX

Hays Colours, UK

paint

powder

Lysopac Orange 3620C

Cappelle, NV, Belgium

paint

powder

Novoperm Orange HL

Clariant Intern. Ltd., CH

paint

powder

Novoperm Orange HL 70

Clariant Intern. Ltd., CH

paint

powder

Novoperm Orange HL70-NF

Clariant Intern. Ltd., CH

paint

powder

Pigment Orange 36

Member(s) of Color Pigments Manufacturing Association, USA

paint, plastics, printing inks

powder

Sudaperm Orange 2915

Sudarshan Chemicals Ind. Ltd, India

paint, plastics and other

powder

Sunfast Orange 36 (271-9036)

Sun Chemical Corp., USA

paint

powder

Symuler Fast Orange 4183H

Dainippon Ink & Chemicals Inc., JP

paint, printing inks

powder

Yorabrite Orange HL

Yorkshire Chemicals plc, UK

paint, plastics, printing inks and other

liquid

dispersion

P. O. 62

Kenalake Orange HP-3GO

Hays Colours, UK

paint, printing inks

powder

Novoperm Orange H5G 70

Clariant Intern. Ltd., CH

paint

powder

P. O. 64

Cromophtal Orange GL

Ciba Speciality Chemicals Inc., CH

printing inks

powder

Cromophtal Orange GP

Ciba Speciality Chemicals

plastics, printing inks

powder

Inc., CH

10 Benzimidazolone Pigments and Related Structures Table 10.4 Continued

C. I. name/ Trademark

Manufacturer

Main applications

Physical

form

Hornapol Orange PO — 536-T

Ciba Speciality Chemicals Inc., CH

plastics

masterbatch

Orange EMD-218

Sumika Color Co. Ltd, JP

plastics

powder

Orange GP

Keystone Aniline Corp., USA

plastics, printing inks

powder

Orange PEC-218

Sumika Color Co. Ltd, JP

plastics

granule

Pigment Orange 64 P. O. 72

Member(s) of Color Pigments Manufacturing Association, USA

plastics, printing inks

powder

PV Fast Yellow H4GL01

Clariant Intern. Ltd., CH

plastics

powder

P. R. 175

Novoperm Red HFT

Clariant Intern. Ltd., CH

paint

powder

PV Fast Red HFT

Clariant Intern. Ltd., CH

plastics

powder

P. R. 176

Aquanyl P Carmine HF3C 13-3166

Clariant Intern. Ltd., CH

paint

powder

Flexonyl Carmine HF3C-LA

Clariant Intern. Ltd., CH

decorative laminates, paper

liquid

dispersion

Graphtol CarmineHF3C

Clariant Intern. Ltd., CH

printing inks

powder

PV Carmine HF3C

Clariant Intern. Ltd., CH

plastics

powder

P. R. 185

Epsilon Red LB-1TO28

Sumika Color Co. Ltd, JP

rubber

masterbatch

Hostaprint Carmine HF4C31

Clariant Intern. Ltd., CH

plastics

powder

Microlith Red 4C-K

Ciba Speciality Chemicals Inc., CH

paint, printing inks

powder

Novoperm Carmine HF4C

Clariant Intern. Ltd., CH

printing inks

powder

Pigment Red 185

Member(s) ofColor Pigments Manufacturing Association, USA

paint, printing inks

powder

Table 10.4 Continued

C. I. name/

Manufacturer

Main applications

Physical

Trademark

form

Graphtol Carmine HF4C

Clariant Intern. Ltd., CH

plastics

powder

Simperm Red AHE

WS Simpson & Co., UK

printing inks and other

powder

P. R. 208

Hostaprint Red HF2B 31

Clariant Intern. Ltd., CH

plastics

powder

Hostasin Red HF2B

Clariant Intern. Ltd., CH

Plastics (rubber)

granule

Novoperm Red HF2B 01

Clariant Intern. Ltd., CH

printing inks

powder

Graphtol Red HF2B 01

Clariant Intern. Ltd., CH

plastics

powder

Renol Red HF2B-HW

Clariant Intern. Ltd., CH

solvent based wood stains, marker inks

powder

P. V. 32

Hostaprint Bordeaux HF3R 31

Clariant Intern. Ltd., CH

plastics

powder

Novofil Bordeaux BB

Clariant Intern. Ltd., CH

coloration of viscose

liquid

dispersion

Novoperm Bordeaux HF3R

Clariant Intern. Ltd., CH

printing inks

powder

Graphtol Bordeaux HF3R

Clariant Intern. Ltd., CH

plastics

powder

P. Br. 25

Hostaprint Brown HFR 31

Clariant Intern. Ltd., CH

plastics

powder

Microdis Brown PSR

Colorom SA, Romania

other

paste

Microdis Yellowish

Colorom SA, Romania

other

paste

Brown IGT

Novofil Brown HFR

Clariant Intern. Ltd., CH

coloration of viscose

liquid

dispersion

PV Fast Brown HFR 01

Clariant Intern. Ltd., CH

plastics

powder

Renol Brown HFR-HW

Clariant Intern. Ltd., CH

solvent based wood stains and marker inks

powder

10.7

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