Priderite Pigments

The BaNiTi yellow priderite pigments are weaker and greener than the NiSbTi DR pigments. Their commercial formulas were developed mostly by empirical test­ing. The DCMA handbook has their chemistry incorrectly listed as 2NiO x 3BaO x 17TiO2, which would result in the presence of secondary phases. Some of the stoichiometry confusion is due to complex composition of the naturally occurring mineral [30] that contains a large number of elements.

The priderite structure is related to the hollandite structure and can give a sin­gle-phase product over a considerable range of stoichiometries near BaNiTi7O16. These Sb-free pigments were initially sold as heavy metal free pigments.

6.2.3

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