Uses

Total production of iron blue in 1975 was ca. 25,000 t a-1, but in 1995 it was only ca. 15,000 t a-1. A value of 9000 t a-1 was estimated for 2002. The main consumer

Tab. 3.6: Physical and chemical properties of iron blue pigments (Vossen Blau® and Manox® Blue Manox® Blue grades).

Type VOSSEN

VOSSEN

VOSSEN

MANOX®

MANOX®

BLAU®

BLAU®

BLAU®

Blue 460

EASISPERSE®

705

705

724

D

HSB 2

LSg)

Color Index Number 77510

77510

77510

77510

77510

Color Index Pigment 27

27

27

27

27

Tinting strengtha) 100

100

100

115

95 h)

pure blue

pure blue

pure blue

pure blue

pure blue

Oil absorptionb), 36-42 g/100 g

40-50

36-42

53-63

22-28

Weight loss on 2-6

2-6

2-6

2-6

2-6

dryingc), %

Tamped densityd), 500

200

500

500

550

g L

Densitye), g cm-3 1.9

1.9

1.9

1.8

1.8

Mean diameter of 70

70

70

40

80

primary particles, nm Specific surface areaf), 35 m2 g 1

35

35

80

30

Thermal stability, °C 150

150

150

150

150

Resistance to acids very good

very good

very good

very good

very good

Resistance to alkalines poor

poor

poor

poor

poor

Resistance to solvents very good

very good

very good

very good

very good

Resistance to bleeding very good

very good

very good

very good

very good

a) DIN ISO 787/XVI and DIN ISO 787/XXIV. b) DIN ISO 787/V, ASTM D 281, or JIS K 5101/19 (JIS: Japanese Industrial Standard). c) DIN ISO 787/II, ASTM D 280, or JIS K 5101/21. d) DIN ISO 787/XI or JIS K 5101/18. e) DIN DIN ISO 787/X or JIS K 5101/17. f) DIN 66131. g) LS = Luftstrahlmtihle (air jet mill). h) Surface-treated easily dispersible type.

in Europe and USA is the printing ink industry. The second largest use in Europe, especially of micronized iron blue pigments, is for coloring fungicides. Use in the paint industry is insignificant.

3.6.4.1

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