Polymer Chain Length

Kinetic Chain Length v is defined as the number of molecules reacting with a reactive centre from its formation to its termination.

V=R[> = Be = kp [M][M~] = kp [M][M‘]

Rt Ri 2kt [M ]2 2fkd[l]

thus;

kp[M] _ kg[M]2 2kt [M*] 2kt Rp

So that the Kinetic Chain Length is inversely proportional to the rate of polymerisation.

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