Refractive index

Refractive index is a characteristic property of solvents and is very sensitive to the composition of solvent blends. Therefore, it is use-

Table 4.2: Properties of some important representative solvents

Solvent

BP

[°C]

ST

[dyne/cm]

Density [g/ml] at 20 °C

ER

FP

[°C]

Hydrocarbon solvents

Mineral spirits (low aromatic)

182-190

26

0.79

200

63

Solvesso 100

155-181

29

0.88

40-45

41

Xylenes

137-142

27.9-29.6

0.87

17

28

Toluene

110-111

27.7

0.87

6.1

7

Dipentene

174-181

26

0.86

50

Alcohols and glycol ethers

Isopropanol

82

23

0.79

11

12

n-Butanol

117.7

24.2*

0.81

33

34

2-Ethylhexanol

182-186

28.7

0.83

1210

73

2-Butoxy ethanol

169-172

26.6

0.90

136

62

1-Propoxy-2-

propanol

149

25.4*

0.88

60.5

48.3

Esters and glycol ether esters

Ethyl acetate

76-78

23.9

0.90

3

-4

Butyl acetate

124-129

25.1

0.88

12.1

27

PGMEAc

140-150

26.4

0.97

30.2

46

Ketones

Acetone

56

25.2

0.79

2

-18

Methyl ethyl ketone

2.7

Methyl isobutyl ketone

114-117

23.6

0.80

7.6

16

Isophorone

215

31.6

0.92

330

88

BP = boiling point or range; ST = surface tension at 20 °C, * at 25 °C; ER = relative evapo­ration rate (diethyl ether = 1); FP = flash point by closed cup; PGMEAc: propylene glycol monomethyl ether acetate (Note: Properties are selected from different resources without claiming to be complete and accurate)

ful for checking purity and uniformity of solvent blends. Refrac­tive index is mainly determined by the hydrocarbon backbone of a substance. In a homologous series, the refractive index increases with increasing length of the carbon chain, and decreases with increasing branching. The presence of cycloaliphatic and aromatic structures increases the refractive index of solvents.

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