Polyamides are polymers with amide linkages (-NH-CO-) in their backbone structures. A well-known example of this type of polymer is nylon, the condensation product of an aliphatic dicarboxylic acid with aliphatic diamines, which was originally developed for replacement of silk. Very high MW and poor solubility of nylon makes it unsuitable for coating applications. Polyamides suitable for coatings are produced from condensation of aliphatic diamines with dimerized fatty acids. Two types of commercial products are offered: (a) thermosetting (reactive) and (b) thermoplastic (non-reactive). The dibasic fatty acids commonly used to manufacture polyamides are prepared by dimerizing unsaturated C18 fatty acids from vegetable oils such as linseed, soybean, or tall oils. The polyamines commonly used are polyethylene polyamines of various chain lengths, such as diethylenetriamine, an example of a simple linear polyethylene polyamine used for making reactive polyamides, while diamines such as ethylenediamine are commonly used for thermoplastic polyamides.
Polyamides
17 октября, 2015 Pokraskin