Monoazo pigments are obtained by coupling a diazonium salt of a substituted aromatic amine with a suitable coupling agent. Acetoa — cetic arylides are used as coupling agents to yield a range of yellow pigments generically known as arylamide yellow, while b-naphthol is used for orange and red pigments generically known as b-naph- thol red. Another important group of pigments, an extension of the b-naphthol red pigments, use arylides of 2-hydroxy-3-naphthoic acid as coupling agents and are known as naphthol AS pigments. Most monoazo pigments have poor heat stability along with poor solvent and migration resistance that limit their applications. They are used extensively in alkyd-based architectural coatings, in emulsion paints and in printing inks. Typical examples are Pigment Yellow 1, 3, 73, 74 and 98, Pigment Orange 5, Pigment Red 3, 4 and 6 and Pigment Red 2, 12, 23 and 112. Some examples are shown in Figure 3.9.
Monoazo pigments
26 ноября, 2015 Pokraskin