Hydrophobically modified ethoxylated urethane thickeners, also known as polyurethane thickeners, are a more recent type of associative thickeners that are more popular for premium quality paints with low pigment volume concentration, which require excellent flow and leveling, and better spatter resistance and coverage. Alkyd-like rheology, hydrophobic properties, and enzyme resistance are some of the other merits of these thickeners. They are composed of hydrophilic polymers such as polyethylene glycol connected through urethane linkages and terminal hydrophobic groups such as oleyl, stearyl, dodecylphenyl, and nonylphenyl. The composition of the hydrophobic segment is very important for the rheological characteristics because the associative characteristics are derived from the adsorption behavior of these groups. Linear or comb-like structures are more common for polyurethane thickeners. Sag resistance and compatibility with glycol-containing pigment concentrates are the main limitations of hydrophobically modified ethoxylated urethane thickeners.
Hydrophobically modified ethoxylated urethanes
29 декабря, 2015 Pokraskin