Epoxy resins are a very important class of thermosetting synthetic polymers used in coatings, adhesives and composites. Epoxy resins are characterized by having three-membered epoxy (also called oxirane or epoxide) functional groups as reactive sites for cross-linking. A typical terminal epoxy group, as depicted below, is commonly known as a glycidyl group.
Glycidyl group
These resins have been commercially available for more than half a century and are used in a diverse range of applications such as coatings, plastics, adhesives, and construction chemicals due to their important characteristics, as listed below.
• Excellent adhesion to a wide range of substrates
• Chemical and water resistance
• Corrosion resistance
• High electrical resistance
• Better heat resistance than most general binders used in coatings
• Resistance to hydrolysis
• Excellent toughness, hardness and flexibility
• Ability to have properties varied or balanced through chemistry
• Wide latitude of curing agents and chemistries.
Besides these excellent characteristics, one major limitation associated with common classes of epoxy resins is their poor durability in exterior conditions. Nevertheless, epoxy resins have been the workhorse of high performance polymers for protective coatings where high corrosion and chemical resistance are important.