Dry films are also subject to microbiological attack by fungi and algae, which impairs the aesthetic appearance of the film by discoloration or patching. In certain situations, this also affects film integrity and hence performance of the coatings. Dry-film preservatives are aimed at preventing the growth of bacteria, fungi, and algae on the paint film surface. As opposed to in-can preservatives, the solubility in water and volatility of dry film preservatives should be as low as possible in order to prevent leaching from the film and to ensure longterm film protection.
Some important examples of dry film preservatives include benzimidazoles such as carbendazim, octylisothiazolinone, carbamates and dithiocarbamates such as thiram, zinc pyrithione and chlorotha — lonil. Representative examples are shown in Figure 5.23. As with in-can preservatives, the optimum use levels should be determined by experiments.