Pseudo Sulfur Dyes

The term “pseudo (or synthetic) sulfur dyes” refers to dyes that have application properties similar to those of sulfur dyes but are obtained by the insertion of mer — capto groups or their precursors into the dye precursors or pigments rather than by the classical sulfurization method. These dyes thus have some of the character­istics of sulfur dyes.

The principal chromophores in pseudo sulfur dyes are copper and cobalt phthalocyanines, e. g., in C. I. Sulphur Green 25 (16), and the perylene tetracar — boxylic diimide structure in C. I. Sulphur Red 14 [81209-07-6] and C. I. Solubilised Sulfur Red 11 [61969-41-3] (17). In contrast to the sulfur dye made from Cu phthalocyanine, the cobalt derivative can be applied with dithionite.

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Some special reactive dyes that can be applied by sulfur-dye methods and can also be combined with sulfur dyes represent a special case. An example is C. I. Solubilised Sulfur Red 11. These dyes contain no thiolate groups at all.

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