History

A literature search on the specified titanate pigments yielded the 22 independent patents listed in Table 6.4. The majority of the patents deal with DR pigments. They cover compositions, processing, and improved properties. The older patents were concerned with ceramic applications, while the newer patents are primarily targeted at improved stability in polymers and paints.

Ref. Patent No.

Inventor

Company

Note

Title

Date Secondary

Rutile Pigments

6

US 1945809

Harbert

Harshaw

CrSbTi

Pigment Composition

02/06/34

7

US 2231829

Harbert

Harshaw

CrWTi

Ceramic Pigment

08/05/41

8

US 2257278

Schaumann

Du Pont

(Ni, Co, SB, TI)02

Process for Colored Titanium Pigments

09/30/41

9

US 3022186

Hund

Bayer

Rutile SS

Mixed Phases with a Rutile or Polyrutile Structure

02/20/62

10

US 3832205

Lowery

Ferro

MNbTi

Pigments of Substantially Ternary System Having Oxides of Columbium and Transitional Elements

08/27/74

11

US 3956007

Modly

Kewanee

NiWZnCeMgLiTi Antimony-Free Yellow Pigments and Their Preparation

05/11/76

12

BR 1541979

Mansmann

Bayer

Rutile nuclei

Production of Improved Chromium Rutile Pigments

03/14/79

13

DE 2936746

Seitz

BASF

Coatings

Process for the Manufacture of Rutile Mixed Phase Pigments

03/19/81

14

US 4450012

Messer

Bayer

Coated

Flocculation-resistant, Mixed Phase Pigments Having a Rutile Structure, Process for their Preparation, and Their Use

05/22/84 EP075197

15

US 4844741

Knittel

Lacke&Farben

0.1-2.0%Mg

Thermostable Rutile Mixed Phase Pigments

07/04/89 EP233601

16

US 4917735

Rademachers

Bayer

Indirect Rotary

Process for the Production of Rutile Mixed-Phase Pigments

04/17/90

17

US 4919723

Wilhelm

Bayer

0.01-0.25%Li

Rutile Mixed Phase Pigments with Improved Coloristic Properties

04/24/90 EP318783

18

US 4919726

Rademachers

Bayer

Direct Rotary

Process for the Production of Rutile Mixed-Phase Pigments

04/24/90

19

US 5006175

Modly

Engelhard

(MnWLiCe)Ti

High Infra Red Reflecting Brown Rutile Pigment Compositions

04/09/91

20

US 5108508

Rademachers

Bayer

Spray Dry

Rutile Mixed Phase Pigment Microgranulates, a Process for Their Preparation and Their Use

04/28/92

21

US 5192365

Modly

Engelhard

CoWLiCeTi

Buff Rutile Pigment Compositions

03/09/93

22

EP 415478

Aderhold

Mitsui Mining +

Sb-doped Sn02

Electrically Conductive Rutile Mixed-Phase Pigment, Process for the Manufacture of these Pigments

01/12/94

23

US 5496404

Gaedecke

BASF

Prep for rotary

Process for Preparing Inorganic Pigments of Particular Particle Size

03/05/96

Priderite Pigments

24

Br1214361

Batchelor

Harrison Mayer

Priderite

Improvements in Pigments

12/02/70

Pseudobrookite Pigments

25

US 4036662

Rademachers

Bayer

PBrookite

Metal Additions to Pigments of Pseudobrookite-Titanium Dioxide Structure

07/19/77

26

US 4084984

Hund

Bayer

PBrookite

Temperature-Stable Inorganic Yellow Pigments

04/18/78

27

EP 949202

Katamoto

Toda Kogyo

PBrookite

Heat Resistant Yellow Pigment

10/13/99

Table 6.4 Patents for Titanate Pigments.

56 I 6 Titanate Pigments: Colored Rutile, Priderite, and Pseudobrookite Structured Pigments

6.2.1

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