SUMMARY

Vinyl acetate homopolymers are simply-made adhesive bases manufactured by addition polymerization in the presence of water and stabilizers. They are made commercially by the batch reactor process or by the Loop reactor continuous process. External plasticizers such as dibutyl phthalate are often added to confer flexibility and to lower the temperature at which they form a film on drying. Higher-quality products may be made by the copo­lymerization of ethylene with vinyl acetate to form an EVA. This involves the safe hand­ling of ethylene gas under high pressure, and the plant required is more complex and considerably more costly. The Loop process has considerable attraction in the field of pressure polymerization.

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