Borax

Borax (sodium tetraborate) in the presence of small amounts of sodium hydroxide is the most widely used additive to starch-based adhesives. It is commonly used in dextrin adhesives, where it increases the viscosity and acts as a tackifier and viscosity stabilizer. These effects are particularly important in machine application of adhesive to substrate. When used in adhesives, borax is often added in amounts up to 10% based on dry starch before the starch is cooked. Enough sodium hydroxide is added to convert the borax to sodium metaborate, which is the active boron species in thickening. The metaborate is able to hook two starch molecules together, forming a complex (Fig. 5) [10]. If additional sodium hydroxide is added, the complex will dissociate; the viscosity of the suspension will begin to decrease with increasing sodium hydroxide [11].

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