And 2,5,7-Aminonaphtholsulfonic Acids (Gamma and J Acids) from /J-Naphthylamine

These two important sulfonic acids can be prepared in various ways. Three methods are used for preparing у acid, while J acid, so far as is known, is prepared only from naphthylamine, although by varying procedures. The starting material in all cases is /З-naphthol; the reac­tions involved are shown in the following scheme. We shall describe here only the preparations starting from /З-naphthylamine. The pro­cesses starting from ^-naphthol and its sulfonic acid derivatives are de­scribed briefly in the technical observations following the preparation of J acid.

Подпись: G acidПодпись: NH,Подпись: Amino-G acidПодпись: NH,Подпись: // ^-Naphthylamineimage142Подпись: 2,8- Dihy droxynaph thalene-6-sulfonic acidimage143OH

I

*

OH

image144

HO, S

2- Amino-8-naphthol-6-
sulfonic acid (Gamma acid)

image145

H03S

NH,

OH

Подпись: S03H image147

2-Amino-5- naphthol-7-
sulfonic acid (iso-Gamma
acid, J acid)

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