Waxes are used primarily in HMA formulations. Waxes are generally highly crystalline hydrocarbons. Waxes are added to HMA formulations to lower cost and decrease viscosity. Some of the HMA properties that are affected by wax content are the softening point and open time. Typically, waxes are thermally stable. During high-temperature storage and compounding, however, waxes can discolor very rapidly. Degradation of a wax can result in a reduction in the thermooxidative stability of the overall HMA formulation. As shown in Fig. 14, the addition of an antioxidant during static oven aging at
Figure 14 Stabilization of a microcrystalline wax: color formation during oven aging at 177°C (350°F). |
177°C (350°F) of a microcrystalline wax can greatly reduce the degree of discoloration. The less volatile AO-2, at lower concentrations, significantly outperforms the more volatile AO-1. This reinforces the importance of volatility when an antioxidant is selected for a high-temperature application.