Plasma-Induced Grafting

As effective as these surface modification processes might be, they present limitations in terms of the extent to which the surfaces of polymers can be modified. Plasma-induced grafting offers another method by which chemical functional groups can be incorporated. In this process, free radicals are generated on the surface of a polymer through the use of an inert gas plasma. Because of the nonreactive nature of the inert gas plasma, surface chemical modification of the polymer does not occur. If the polymer surface that has been

Material

Plasma Chemistry

Adhesive

Bond Strength (psi)

Failure

Mode

Ref.

Vectra

Control

Epoxy

939

Adhesive

8

A625

Oxygen plasma

Scotchweld

1598

Cohesive

Ammonia plasma

2216 (3M)

1240

Cohesive

Noryl

Control

Epoxy

617

Adhesive

8

731

Oxygen plasma

Scotchweld

1485

Adhesive

Ammonia plasma

2216 (3M)

1799

Cohesive

Ultem

Control

Epoxy

186

Adhesive

8

1000

Oxygen plasma

Scotchweld

1939

Cohesive

Ammonia plasma

2216 (3M)

2056

Cohesive

Rynite

Control

Epoxy

683

Adhesive

16

530/935

Plasma treatment A

5875

Cohesive

Plasma treatment B

6067

Cohesive

Tefzel

Control

Epoxy

10

12

Ammonia plasma

Uniset

202

O2/SF6 plasma

D276

293

treated in this fashion is exposed to vapors of unsaturated monomers, these monomers then get attached to the surface of the polymer. A variety of vinyl monomers are available and the possibilities for incorporating many different chemical functional groups are end­less. Unlike surface modification, this is a two-step process that adds a degree of complex­ity. Few studies have appeared in the open literature, with the majority of such processes being used in proprietary applications [41,42]. This process is mentioned here as an option that is available to the surface engineer.

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