Melamine formaldehyde can be crosslinked at elevated temperatures with both hydroxyl and carboxyl functional groups. (See thermosetting acrylics chapter for reaction mechanisms.) The temperature required is at least 120°C, at which point the hydroxyl group will react, but the carboxyl group needs a slightly higher heat input, approximately 150°C. Systems are unlikely to require an acid catalyst because of the catalytic effects of the polymerisation catalysts and surfactants in the acrylic latices. If required, p-toluene sulphonic acid is the most suitable (typically at levels of 0.2 — 0.4%). Alternatively, the melamine resin could be incorporated in an unneutralised, acidic emulsion, which reduces the cure temperature, but will sacrifice stability.
Methylated polymers
5 октября, 2015 Malyar