Hydroxyl Functionality

Hydroxyl Functionality Hydroxyl Functionality

Usually conferred by acrylic and methacrylic esters which have been substituted with an hydroxyl group. Examples of common hydroxyl substituted monomers are:

Подпись:2 hydroxy propyl methacrylate

Figure 1-24

(i) Carboxyl Functionality

Подпись: CH2=CH C —OH Подпись: CH2= CCH, I C —OH

Acrylic and methacrylic acid are most commonly used to introduce carboxyl functionality into a polymer.

Подпись: о Acrylic Acid О

Methacrylic Acid

Figure 1-25

(ii) Epoxy Functionality

Hydroxyl Functionality Hydroxyl Functionality Подпись: CH3 I CH2= C - C - O — CH2—CH — CH2 II / о о

Glycidyl acrylates and methacrylate are generally used to introduce epoxy groups into the polymer

Подпись: Glycidyl AcrylateGlycidyl Methacrylate

Figure 1-26

Glycidyl acrylate is volatile and toxic and finds limited use. Glycidyl methacrylate is much less hazardous and is normally used in preference. Suppliers of these monomers are difficult to obtain outside Japan.

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