13 ноября, 2015 
Pokraskin In the EC lead chromate and lead chromate pigments must be appropriately labeled. Such substances must carry the symbols and indications of danger T, Toxic (skull and
crossbones) and N, Dangerous for the environment (dead fish/tree) [3.144]. Additionally, the following risk (R) and safety phrases (S) have to be applied:
R61 May cause harm to the unborn child.
R33 Danger of cumulative effects.
R40 Limited evidence of carcinogenic effect.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R62 Possible risk of impaired fertility.
S53 Avoid exposure — obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
560 This material and its container must be disposed of as hazardous waste.
561 Avoid release to the environment. Refer to special instructions/safety data sheets.
According to Council Directive 1999/45/EC on Classification, Packaging and Labeling of Dangerous Preparations (Preparations Directive) [3.145] in conjunction with the 28th Adaption to Council Directive 67/548 on Classification, Packaging and Labeling of Dangerous Substances, Nota 1 [3.144], such preparations have to be labeled in accordance with the limits set for the single R-phrases if a lead content of 0.5% Pb in the preparation is exceeded.
With respect to improved protection of public health, special restrictions on can — cerogenic and teratogenic substances and their corresponding preparations have been established by the Council Directive 94/60/EC (14th amendment of Council Directive 76/769/EEC) [3.146].
In accordance with the 14th amendment of Council Directive 76/769/EEC [3.146] and revised ChemVerbV [3.147], lead chromate based pigments and preparations are no longer permitted to be used by private consumers and have to be labeled with the phrase “Only for industrial purposes”.
Lead-containing coatings and paints with a total lead content exceeding 0.15% of the total weight of the preparation must carry the phrase: “Contains lead. Should not be used on surfaces liable to be chewed or sucked by children” in accordance with Council Directive 1999/45/EC [3.145] and German GefStoffV [3.147].
Lead chromate pigments are not permitted for use in packaging material intended to come in contact with food [3.148] or for coloring toys [3.149].
For road transport in accordance with GGVSE [3.150] and ADR 2003 [3.151], lead chromate pigments and lead chromate containing preparations are assigned to class
6.1 (T5), III (UN-No. 2291) and have to be labeled with hazard symbol 6.1 (Toxic), if the lead content soluble in hydrochloric acid [c(HCI) = 0.07 mol L-1] exceeds 5%. For maritime transport in accordance with IMDG code [3.152] such lead chromate pigments and lead chromate-containing preparations have to be labeled additionally as marine pollutant.
136 I 3 Colored Pigments
3.5
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