Analysis

The industrial synthesis of inorganic pigments is strictly controlled by qualitative and quantitative chemical analysis in modern, well-equipped physicochemical test laboratories. Quantitative chemical and X-ray analysis is carried out on raw mate­rials, intermediates, and substances used for aftertreatment, but most importantly on the final products, byproducts, and waste products (wastewater and exhaust gas). This serves to fulfill not only quality requirements but also the demands of environ­mental protection. Quality control, carried out in specially equipped laboratories, in­cludes testing of physical and technical application properties [1.7, 1.8]. Information on quality requirements for inorganic pigments is widely available in international (ISO), European (EN), and national standards (e. g., AFNOR, ASTM, BSI, DIN) [1.9, 1.10]. Standard analytical methods and conditions of delivery for the most impor­tant inorganic pigments are given in Table 1.1. Further information is given in later sections.

Tab. 1.4: Classification of inorganic colored pigments.

Chemical class

Green

Blue-green

Blue

Violet

Red

Orange

Yellow

Brown

Oxides and oxide-hydroxides

Iron oxide pigments

iron oxide red

iron oxide orange

iron oxide yellow

iron oxidt brown

Chromium oxide pigments

chromium

oxide

chromium

oxide

hydrate

green

Mixed metal oxide pigments

cobalt green and blue

chromium

rutile

orange

nickel rutile yellow, chromium rutile yellow

zinc iron spinel, Mn-Fe brown

Sulfide and

sulfoselenide

pigments

cadmium

sulfose­

lenide

cerium

sulfide

cadmium sulfide, (Cd, Zn)S

Chromate pigments

chrome

green

molybdate

red

chrome

orange

chrome yellow, zinc yellow

Ultramarine

pigments

ultramarine green, blue, violet, and red

Iron blue pigments

iron blue

Others

manganese

blue

cobalt

manganese

violet

(Ca, La)Ta(0,N)3

naples

yellow,

bismuth

vanadate

 

Подпись: 7.2 General Chemical and Physical Properties 13

1.2.1.3

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