Nomenclature — the Colour Index system

In modern scientific and techno-commercial publications, pigments are frequently discussed using a universally accepted standard coding system known as the Colour Index, which was jointly deve­loped by the Society of Dyers and Colourists in the United Kingdom and the Association of Textile Chemists and Colorists in the United States. The Colour Index identifies each colorant by giving the com­pound a unique Colour Index name and a Colour Index number. The five or six digit Colour Index number is allocated to a colorant according to its chemical constitution as described in Table 3.1.

Table 3.1: Colour Index (CI) constitution numbers

Chemical class

CI numbers

Chemical class

CI numbers

Nitrosol

100000-102999

Thiazole

490000-493999

Nitro

103000-109999

Indamine

494000-496999

Monoazo

110000-199999

Indophenol

497000-499999

Diazo

200000-299999

Azine

500000-509999

Stilbene

400000-407999

Oxazine

510000-519999

Diphenylmethane

410000-419999

Thiazine

520000-529999

Triarylmethane

420000-449999

Aminoketone

560000-569999

Xanthene

450000-459999

Anthraquinone

580000-729999

Acridine

460000-469999

Indigoid

730000-739999

Quinoline

470000-479999

Phthalocyanine

740000-749999

Methine

480000-489999

Inorganic pigments

770000-779999

The CI generic name is composed of:

• The application class of the colorant (for example, pigment, sol­vent dye, basic dye)

• The hue of the colorant (for example, yellow, blue, violet, red)

• The number (unique within the same group and shade desig­nation)

The Colour Index, names for pigments and their abbreviations are shown in Table 3.2.

Table 3.2: Abbreviated Colour Index (CI) names for pigments

Abbreviation

CI name

Abbreviation

CI name

PB

Pigment Blue

PBk

Pigment Black

PBr

Pigment Brown

PG

Pigment Green

PM

Pigment Metal

PO

Pigment Orange

PV

Pigment Violet

PR

Pigment Red

PW

Pigment White

PY

Pigment Yellow

For example, phthalocyanine blue has the Colour Index name Pig­ment Blue 15 (CI PB 15) and the Colour Index number 74160.

For distinguishing pigments with the same chemical composition but a small difference in structure, such as the metal or acid used for salt formation, a subdivision has been made by addition of a digit to the CI name or CI number after a colon. This is also used to distin­guish pigments in which crystal modifications yield products with the same chemical structure but significantly different properties.

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