Surface Wettability Theory

Erickson and Plueddemann suggest that particularly in filled systems, complete wetting of the mineral surface will improve adhesion by physical adsorption that would exceed the cohesive strength of the polymer. However, it is difficult to see how physical adsorption provides bond reinforcement when the polymer is in competition with water and possibly other weakly bonded surface layers, and where chemical bonding is also present [12].

B. Restrained Layer Theory

In effect, this theory postulates a chemical reaction between promoter, polymer, and mineral substrate as in the chemical bond theory but also suggests that the presence of a region of intermediate modulus between polymer and substrate which transfers stress from the high modulus surface to the relatively low modulus polymer. Adhesive technol­ogy has long recognized this principle in specially formulated primers for use when bond­ing rubbery polymers to metals.

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